15 March 2010

Water oxidation advance boosts potential for solar fuel

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Emory University chemists have developed the most potent homogeneous catalyst known for water oxidation, considered a crucial component for generating clean hydrogen fuel using only water and sunlight

The breakthrough, published March 11 in the journal Science, was made in collaboration with the Paris Institute of Molecular Chemistry.

The fastest, carbon-free molecular water oxidation catalyst (WOC) to date "has really upped the standard from the other known homogeneous WOCs," said Emory inorganic chemist Craig Hill, whose lab led the effort. "It's like a home run compared to a base hit."

In order to be viable, a WOC needs selectivity, stability and speed. Homogeneity is also a desired trait, since it boosts efficiency and makes the WOC easer to study and optimize. The new WOC has all of these qualities, and it is based on the cheap and abundant element cobalt, adding to its potential to help solar energy go mainstream.

(EurekAlert!)

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