Understanding the key elements of biofuel combustion is an important step toward insightful selection of next-generation alternative fuels. And that's exactly what Lawrence Livermore and Sandia national laboratories researchers intend to do.
In a new paper on the cover of the May 10 edition of the journal Angewandte Chemie, Sandia researcher Nils Hansen and Lawrence Livermore scientist Charles Westbrook take a look at the vastly diverse and complex chemical reaction networks of biofuel combustion.
The paper, "Biofuel Combustion Chemistry: From Ethanol to Biodiesel," examines the combustion chemistry of those compounds that constitute typical biofuels, including alcohols, ethers and esters.
Biofuels such as bioethanol, biobutanol and biodiesel are of increasing interest as alternatives to petroleum-based transportation fuels. According to Hansen and Westbrook, however, little research has been done on the vastly diverse and complex chemical reaction networks of biofuel combustion.
In general, the term biofuel is associated with only a few select chemical compounds, especially ethanol (used exclusively as a gasoline replacement in spark-ignition engines) and very large methyl esters in biodiesel (used as a diesel fuel replacement in diesel engines). The biofuels are oxygenated fuels, which distinguishes them from hydrocarbons in conventional petroleum-based fuels.
While much discussion surrounding biofuels has emphasized the process to make these alternative fuels and fuel additives, Hansen and Westbrook for the first time examined the characteristic aspects of the chemical pathways in the combustion of potential biofuels.
(Bio Fuel Daily)
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